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New Synthetic Routes to Polyoxometalate Containing Ionic Liquids

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In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and Mößbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials.

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Detail Information

Series Title

BestMasters

Call Number

-

Publisher

Wiesbaden : Springer Spektrum Wiesbaden., 2015

Collation

XXI, 122

Language

English

ISBN/ISSN

2625-3577

Classification

NONE

Content Type

text

Media Type

computer

Carrier Type

online resource

Edition

1

Subject(s)

Inorganic Chemistry
Catalysis
Industrial Chemistry

Specific Detail Info

-

Statement of Responsibility

Sven Herrmann

Other Information

Cataloger

Lika

Source

https://link.springer.com/book/10.1007/978-3-658-08796-8

Validator

Taufik

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