In his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition …
The dispersion of nanomaterials in liquid crystals, both of the thermotropic and the lyotropic kind, has attracted much interest over recent years. This is in part related to the success of liquid crystals in several applications, in particular flat screen displays, besides others. The dispersion of nanoparticles allows the fine-tuning of liquid crystalline properties and the addition of functi…
Open-access organic chemistry textbook (volumes I and II) in which the main focus is on relevance to biology and medicine. This is a PDF version of a wiki project called Chemwiki at the University of California, Davis. There are also supplementary materials, such as PowerPoint slides and a solutions manual available for this textbook at the Chemwiki website.
Overall, this work identifies key points to be taken into account when drawing up guidelines that govern the use of herbicide-tolerant (HT) crops in order to preserve the effectiveness of this innovation over time. This multidisciplinary expert report, based on an international literature review, assesses the effects of the cultivation of crops possessing HT traits. HT crops may appear to be u…
Chemistry is designed to meet the scope and sequence requirements of the two-semester general chemistry course. The textbook provides an important opportunity for students to learn the core concepts of chemistry and understand how those concepts apply to their lives and the world around them. The book also includes a number of innovative features, including interactive exercises and real-world …
This thesis addresses two fundamental areas in contemporary organic chemistry: synthesis of natural products and catalytic asymmetric synthesis. Firstly, a new methodology, developed by our research group, which allows the asymmetric synthesis of lactones, a structural unit ubiquitous in natural products, was utilised in the synthesis of a number of natural product analogues that showed signifi…
This volume explores the revolutionary fMRI field from basic principles to state-of-the-art research. It covers a broad spectrum of topics, including the history of fMRI's development using endogenous MR blood contrast, neurovascular coupling, pulse sequences for fMRI, quantitative fMRI; fMRI of the visual system, auditory cortex, and sensorimotor system; genetic imaging using fMRI, multimodal …
This book details first the chemistry of hydrogen production from biomass. Solutions to the CO2 issue are given in three chapters, which describe CO2 photo catalytic reduction, CO2 sequestration in terrestrial biomass, and plants as renewable fuels. Further chapters review the selenium cycle in ecosystems, advanced processes to treat water and ecological ways to dye textiles. Society growth…
The emission of dibenzofurans and dioxins from industrial processes is a major environmental concern. Focussing on dibenzofuran, this study tend to improve our understanding of the general oxidation chemistry and to provide a mechanism suitable for future modelling studies.Based on quantum chemical methods, energies, chemical structures and reactions are calculated numerically. Not only stable …
This book covers the advances in the studies of hydrogen-bonding-driven supramolecular systems made over the past decade. It is divided into four parts, with the first introducing the basics of hydrogen bonding and important hydrogen bonding patterns in solution as well as in the solid state. The second part covers molecular recognition and supramolecular structures driven by hydrogen bonding.…